Explain some assembly language commands/Values — 2 by sinbadon

I need to learn and understand how some commands and instructions work in assembly language. I am using a debugging/disassembler programs but I am getting stuck on some commands. I WILL NOT PROVIDE ANY EXE/DLL files… (Budget: $10 – $30 USD, Jobs: .NET, Assembly, C++ Programming, Debugging, x86/x64 Assembler)